Origin and Maturity of Biomarker Aliphatic Hydrocarbon in Wondama Coal Indonesia

Keywords: Biomarker, Gas Chromatography-Mass Spectroscopy (GC-MS), Organic geochemistry, Wondama coal

Abstract

Organic geochemical characterization of Wondama coal samples from the Lengguru Folding Belt has been carried out through the study of its aliphatic hydrocarbon biomarkers. This study is to determine the origin, depositional environment and maturity of coal which is useful for determining the use of coal as an energy source. Aliphatic hydrocarbon biomarkers were identified by using gas chromatography-mass spectroscopy methods which showed the presence of n-alkane homologs (n-C15 - n-C33), which was dominated by n-C31. This indicates that the organic material originates from Angiosperms of terrestrial higher plants. The ratio of pristane to phytane (Pr/Ph) with value of 3.74 indicates that the Wondama coal is buried in an oxic depositional environment. The Carbon Preference Index (CPI) value of 7.82 and the C31αβS/(S + R) ratio of 0.27 indicate low maturity of Wondama coal and is classified into a sub-bituminous coal ranks.

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The existence of long-chain n-alkanes indicates the source of coal organic compounds originated from terrestrial higher plants. Very low abundance of short and medium n-alkane chains indicates low contribution of bacteria, algae and plankton in the formation of coal organic compounds. The existence of n-alkane homologues with distributions such as those obtained in Wondama coal was also found in previous studies. In this study, the presence of pristane and phytane compounds with Pr/Ph = 3.75 in Wondama coal, indicates the depositional environment is oxidic, or tends to be oxidative.
Published
2020-08-31
How to Cite
Zetra, Y., Burhan, R. Y. P., Pratama, A. D., & Wahyudi, A. (2020). Origin and Maturity of Biomarker Aliphatic Hydrocarbon in Wondama Coal Indonesia. Journal of the Indonesian Chemical Society, 3(2), 107. https://doi.org/10.34311/jics.2020.03.2.107